Successive catalytic reactions specific to Pd-based rotaxane complexes as a result of wheel translation along the axle.

نویسندگان

  • Norihito Miyagawa
  • Masahiro Watanabe
  • Takanori Matsuyama
  • Yasuhito Koyama
  • Toshiyuki Moriuchi
  • Toshikazu Hirao
  • Yoshio Furusho
  • Toshikazu Takata
چکیده

Rotaxane-structure-specific Pd-catalyzed rearrangement of propargyl or allyl urethane groups to oxazolidinone moieties proceeded efficiently. The conversion took place successively by the translation of the wheel along the axle, thus providing a novel macrocyclic catalytic system.

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عنوان ژورنال:
  • Chemical communications

دوره 46 11  شماره 

صفحات  -

تاریخ انتشار 2010